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Lasers are now an essential tool in industry for cutting, marking, engraving and welding a vast range of materials.

Metals are commonly worked substrate but organic materials (plastics, paper, wood) are also widely used.

In virtually all the above operations some form of fume is given off as the laser thermally decomposes the substrate to a greater or lesser degree. This fume is a mixture of particulate and gaseous matter.

Fume from materials such as metals and glass is mainly particulate, the majority of which is less than 5µm (microns) in diameter.

Organic materials, particularly plastics, produce much more complex fumes which are investigated below.

Most of the particles are roughly spherical and less than 5µm in diameter. These particles fall within the respirable range and need to be removed from the working environment to prevent bronchial or lung damage.

The gaseous organic compounds produced are known as Volatile Organic Compounds (VOCs).

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VOCs emitted from lasered organic materials:

Aliphatic hydrocarbons

alkanes, alkenes

Aromatic hydrocarbons

benzene, toluene, xylene

Organic Acids

Acrylic acid, Lactic acid, Butyric acid

Aldehydes

formaldehyde, acetaldehyde

Ketones

Acetone

Acrylates

Methyl methacrylate, Butylacrylate

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Additionally some materials have other specific groups e.g. PVC polymers generate HCl, 2 component epoxy polymers yield amines and PET generates THF.

A considerable number of the above have occupational exposure limits set for them. As with the particulate element these gases need removing from the workplace.